Journal Articles Angewandte Chemie International Edition Year : 2016

Molecular Calcium Hydride: Dicalcium Trihydride Cation Stabilized by a Neutral NNNN-Type Macrocyclic Ligand

Abstract

Hydrogenolysis of bis(triphenylsilyl)calcium containing the neutral NNNN‐type macrocyclic amine ligand Me4TACD [Ca(Me4TACD)(SiPh3)2] (2), gave the cationic dinuclear calcium hydride [Ca2H3(Me4TACD)2](SiPh3) (3), characterized by NMR spectroscopy, single‐crystal X‐ray analysis, and DFT calculations. Compound 3 reacted with deuterium to give the deuteride [D3]‐3.

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Chemical Sciences

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Submitted on : Thursday, January 3, 2019-2:09:45 PM

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hal-01968880 , version 1 (03-01-2019)

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  • HAL Id : hal-01968880 , version 1

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Valeri Leich, Thomas Spaniol, Laurent Maron, Jun Okuda. Molecular Calcium Hydride: Dicalcium Trihydride Cation Stabilized by a Neutral NNNN-Type Macrocyclic Ligand. Angewandte Chemie International Edition, 2016, 55 (15), pp.4794-4797. ⟨hal-01968880⟩

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