Hydrosilylation catalysis by an earth alkaline metal silyl: synthesis, characterization, and reactivity of bis(triphenylsilyl)calcium - INSA Toulouse - Institut National des Sciences Appliquées de Toulouse
Article Dans Une Revue Chemical Communications Année : 2014

Hydrosilylation catalysis by an earth alkaline metal silyl: synthesis, characterization, and reactivity of bis(triphenylsilyl)calcium

Résumé

Bis(triphenylsilyl)calcium [Ca(SiPh3)2(thf)] obtained in high yield as a crystalline ether adduct catalyzes the hydrosilylation of activated C–C double bonds efficiently and regioselectively.
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hal-01969530 , version 1 (04-01-2019)

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  • HAL Id : hal-01969530 , version 1

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Valeri Leich, Thomas Spaniol, Laurent Maron, Jun Okuda. Hydrosilylation catalysis by an earth alkaline metal silyl: synthesis, characterization, and reactivity of bis(triphenylsilyl)calcium. Chemical Communications, 2014, 50 (18), pp.2311. ⟨hal-01969530⟩
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